Crystalline Molecular Complexes and Compounds: Structures and Principles, Том 1Oxford University Press, 2005 - 1273 страници This book provides a comprehensive and unified account of the structure and properties of crystalline binary adducts. Perhaps better known as molecular complexes and compounds, these crystals are currently estimated (from molecular recognition studies) to make up one quarter of the world's crystals, providing evidence for some sort of special attraction between the two components. DNA is perhaps the most famous example but others (hydrates, solvates, host-guest inclusion complexes, donor-acceptor compounds) pervade the whole body of solid state chemistry. Although much research has been published, there has never been a comprehensive and unified treatment of the whole field. This book has been designed to fill this gap, comparing and contrasting the various examples and the different types of interaction (hydrogen bonding, inclusion and localized or delocalized charge transfer). More than 600 figures, 200 tables and 3500 references are included in the book. Since most 'parent compounds' form a number of adducts, the fraction of crystalline binary adducts is only going to grow making this account just the 'tip of the iceberg.' |
Съдържание
Structural principles in the classification of binary adducts | 3 |
Historical outline | 17 |
Introduction to Part II | 23 |
Cyclodextrins and some analogs as hosts | 73 |
Crystal chemistry of some DNA oligonucleotides and their | 133 |
oligonucleotideguest structures | 142 |
Introduction to Part III | 199 |
Clathrate inclusion complexes formed by hosts of lesser versatility | 321 |
guests | 431 |
catenated hexagonal unary networks | 446 |
Intercalation complexes | 515 |
30 | 535 |
44 | 542 |
Introduction to Part IV | 561 |
47 | 609 |
metalloid structures clathrasils gas hydrates clathrate | 348 |
Inclusion complexes formed by versatile hosts | 421 |
Други издания - Преглед на всички
Crystalline Molecular Complexes and Compounds: Structures and Principles Frank H. Herbstein Ограничен достъп - 2005 |
Crystalline Molecular Complexes and Compounds: Structures and Principles Frank H. Herbstein Ограничен достъп - 2005 |
Често срещани думи и фрази
a-CD ų acetate acid Acta Cryst analogous anions arrangement asymmetric unit atoms B-quinol base pairs benzene binary cage carboxyl cations cavities CCl4 cell dimensions cell volume Chem chemical chemistry chiral clathrate components composition compounds conformation Crystal data crystal structure crystallographic CS-I CS-II cyclodextrins Dickerson diffraction dimers disordered duplex Dyadin enantiomers enantiomorph enthalpy example formation gas hydrates GICs gossypol guest molecules H₂O Harata Herbstein hexagonal host framework host molecules host-guest hydrogen bonds hydroxyl interactions intercalation isomorphous isostructural kJ/mol layers MacNicol macrocycle methyl minor groove moieties molecular monoclinic native Neidle oligonucleotides orthorhombic oxygen p-xylene packing phase diagram Phenom PHTP polymorphs quinol racemic Refcode References reported Reproduced rhombohedral ring Ripmeester room temperature Saenger shown in Fig similar solid solutions solvent space group stacking symmetry Table TATM tetragonal thiourea triclinic trigonal tunnel axis tunnel inclusion complexes types Uekama unit cell urea Waals water molecules